Product ID:S00707 PDRP
MSDS Date:09/01/1996
FSC:9150
NIIN:00N083593
MSDS Number: CGQZG

SHERWIN-WILLIAMS CO

31500 SOLON RD
SOLON, OH 44139
US

Emergency Phone: 216-566-2917

Info Phone: 800-777-2966

Cage: DO642

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.

BEDFORD HEIGHTS, OH 44146 US

Telephone: 216-292-7400 OR 216-595-8634

Cage: 09800

760.0

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 14%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

760.0

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: 13%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

127.0

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 5%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

250.0

CAS: 107-83-5

RTECS: SA2995000

Fraction By Weight: 3%

OSHA PEL 500 PPM (MFR)

ACGIH TLV: 500 PPM (MFR)

METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 10.77%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM, A2

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

MINERAL OIL, PETROLEUM DISTILLATE, SOLVENT DEWAXED (MILD),

CAS: 64742-65-0

RTECS: PY8038500

Fraction By Weight: 17%

OSHA PEL 5 MG/M3 (MFR)

ACGIH TLV: 5 MG/M3 (MFR)

5.9

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 11%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (LIGHT

CAS: 64742-95-6

RTECS: WF3400000

Fraction By Weight: 5-10%

OSHA PEL N/K

ACGIH TLV: N/K

10.0

CAS: 98-82-8

RTECS: GR8575000

Fraction By Weight: 1%

OSHA PEL 50 PPM, S

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

10.0

CAS: 108-67-8

RTECS: OX6825000

Fraction By Weight: 7%

OSHA PEL 25 PPM (MFR)

ACGIH TLV: 25 PPM (MFR)

BENZENE, 1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE) (SARA

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 10-15%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM

1.7

CAS: 1569-01-3

RTECS: UB9351000

Fraction By Weight: 3%

OSHA PEL N/K

ACGIH TLV: N/K

1.3

CAS: 2807-30-9

RTECS: KM2800000

Fraction By Weight: 3%

OSHA PEL N/K

ACGIH TLV: N/K

LUNG. MINERAL OIL

RTECS: 9999999ZZ

LEGS (PERIPHERAL NEUROPATHY), RSLTG IN

RTECS: 9999999ZZ

PRESENCE OF METHYL ETHYL KETONE. PRLNG OVEREXP TO

RTECS: 9999999ZZ

CARDIOVASCULAR, CENTRAL NERV & REPRO SYS. RPTS HAVE

RTECS: 9999999ZZ

NERV SYS DMG. CHLOROCARBON MATLS HAVE PRDCED SENSIT

RTECS: 9999999ZZ

HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G.,

RTECS: 9999999ZZ

SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY

RTECS: 9999999ZZ

PILOT LIGHTS, & HEATERS; TURN OFF STOVES, ELEC

RTECS: 9999999ZZ

CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING

RTECS: 9999999ZZ

EXPOSE TO TEMPS >120F. HEAT FROM SUNLIGHT,

RTECS: 9999999ZZ

CAUSE CONTR TO BURST. NO SMKNG IN AREA OF USE. DO

RTECS: 9999999ZZ

SURFS. HEAT &/OR UV RADIA MAY CAUSE FORM OF HCL

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERV SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. OVEREXP TO METHYLENE CHLORIDE CAN RAISE LEVEL OF CARBON
MONOXIDE IN BLOOD. HDCH, DIZZ , NAUS, & LOSS OF COORD ARE
INDICATIONSOF EXCESS EXPOS TO VAPS/SPRAY MISTS. REDNESS &
ITCH/BURNING (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: IARC MONO, SUPP, VOL
7, PG 194, 1987: GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:
ANTIC (ING 14)
Effects of Overexposure:HLTH HAZ: SENSATION MAY INDICATE EYE/EXCESS
SKIN EXPOS. CHRONIC: LAB ANIMALS EXPOSED TO HIGH LEVELS OF
METHYLENE CHLORIDE IN LIFETIME STUDIES HAVE DEVELOPED CANCER. THERE
IS NO EVIDENCE TO DATE THAT M ETHYLENE CHLORIDE CAUSES CANCER IN
HUMANS. PRLNG & RPTD EXPOS TO HEXANE MAY CAUSE DMG TO NERVE TISS OF
ARMS & (ING 15)
Medical Cond Aggravated by Exposure:CARDIOVASCULAR PROBLEMS MAY BE
AGGRAVATED BY OVEREXPOSURE TO METHYLENE CHLORIDE.

First Aid:INHAL:REMOVE FROM EXPOS. RESTORE BRTHG. KEEP WARM & QUIET.
SKIN:WASH THORO W/SOAP & WATER. REMOVE CONTAM CLTHG, LAUNDER BEFORE
REUSE. EYE:FLUSH W/LGE AMTS OF WATER FOR AT LEAST 15 MIN. GET MED
ATTN. I NGEST:NEVER GIVE ANYTHING BY MOUTH IF UNCON. GIVE CONSCIOUS
PERS SEVERAL GLASSES OF WATER. IF VOMIT NOT SPONT, INDUCE VOMIT BY
GENTLY TOUCHING BACK OF THROAT W/FINGER. KEEP AIRWAY CLEAR. GET MED
ATTN.

Flash Point:<0F,<-18C
Lower Limits:0.7%
Upper Limits:16.9%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH APPRVD PRESS DEMAND SCBA & FULL
PROT EQUIP . WATER SPRAY MAY BE INEFFECTIVE. IF WATER USED, FOG
NOZZ PREF. WATER MAY BE USED TO COOL (SUP DAT)
Unusual Fire/Explosion Hazard:CLSD CONTRS MAY EXPLODE (DUE TO BUILD-UP
OF PRESS) WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, ELEC
EQUIP, SPKS & OPEN FLAME. APPLICATION TO HOT (SUP DAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:BEFORE INITIAL USE, CONSULT OSHA'S STD
FOR OCCUP EXPOS TO METHYLENE CHLORIDE (29 CFR 1910.1052). USE ONLY
W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST.
Other Precautions:AVOID CONT W/SKIN & EYES. CONTENTS EXTREMELY FLAM.
KEEP AWAY FROM HEAT, SPKS, OPEN FLAME. VAPS WILL ACCUM READILY &
MAY IGNITE EXPLO. DURING USE & UNTIL ALL VAPS ARE GONE: KEEP AREA
VENTILATED; DO NOT SMOKE; EXTING ALL FLAMES, (ING 21)

Respiratory Protection:A NIOSH APPROVED AIR SUPPLIED RESPIRATOR MUST BE
WORN, UNLESS AIR MONITORING DEMONSTRATES VAPOR/MIST CONCENTRATIONS
ARE BELOW PERMISSIBLE LIMITS. FOLLOW RESPIRATOR MANUFACTURER'S
DIRECTIONS FOR RESPIR ATOR USE.
Ventilation:LOC EXHAUST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS
MAINTAINED BELOW APPLIC EXPOS LIMITS. CONT NEHC FOR MORE INFO .
Protective Gloves:VITON, NITRILE RUBBER, PVA.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC: CLSD CONTRS TO PVNT PRESS BUILD-UP & POSS
AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: SURFS
REQUIRES SPECIAL PREC. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS
MAY CAUSE HL TH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED
ATTN. THERMAL DECOMP PRODS MAY INCL HCL & PHOSGENE .

Boiling Pt:B.P. Text:>0F,>-18C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.76
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER
Percent Volatiles by Volume:79

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, HYDROGEN CHLORIDE. PHOSGENE .

Waste Disposal Methods:WASTE MAY BE HAZARDOUS AS DEFINED UNDER RCRA 40
CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLICABLE EPA HAZ WASTE NUMBERS. DO NOT INCINERATE. DEPRESSURIZE
CONTR. DISPOSE OF I/A/W FE D, STATE & LOC REGULATIONS REGARDING
POLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.